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The most important factors that influence the α/β ratio in glycosylation reactions are (1) the substituent at the C-2 position (participating versus nonparticipating), (2) orientation of the substituent at the C-2 position (equatorial versus axial), (3) type of substituents in the acceptor and donor molecules, (4) type of leaving group, (5) type of promoter, (6) solvent, and (7) temperature.
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Various types of leaving groups, such as amines, can be released from derivatives of 3′,5′-dimethoxybenzoin (33).
In case such a substituent is stable to conditions required to activate other types of leaving groups, it can be used as glycosyl acceptor as well.
Takahashi and co-workers(196) have reported synthesis of a trisaccharide, based on the difference in reactivity between glycosyl donor and acceptor accomplished by use of different types of leaving groups with different reactivity.
Planned type of school leaving certificate: A single item with three answer categories was used to assess the planned type of school leaving certificate.
Blaming a physio for a bad result is the "wrong type of leaves" excuse of the footballing world.
Bosses can lead by example, by taking the same type of leave they expect their employees to take.
Many progressive Fortune 500 companies offer some type of leave.
It has definitions and details about each type of leave, and it also has specific examples of how a federal worker might combine different types of leave in a way that makes the most sense for his or her family.
Work status was collected in a subset of 212 respondents and was categorized as normal duties, neck-related sick leave, or other type of leave.
Contracted physicians are generally young residents, recent graduates or people who work as substitutes, filling in for those on maternity leave, vacation or some other type of leave.
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