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Subsequent radical additions to the monomer, vinyl chloride, proceed the same way, with the result that polyvinyl chloride contains chlorine atoms predominately on alternate carbon atoms: This type of reaction, termed head-to-tail polymerization, is characteristic of most vinyl monomers, regardless of the type of initiator employed.
Depending upon the type of initiator, polymerization of ethyl 2-cyanoacrylate resulted in either the formation of neat polymer nanofibers (∼200 nm in diameter) or thin films.
The type of initiator used influences the surface activity of entering oligomers and is therefore also an important factor in obtaining the correct structure.
The detonability limits, which are dependent on the facility geometry and type of initiator used in this study, were measured for fuel-lean and fuel-rich hydrogen air mixtures and stoichiometric hydrogen air mixtures diluted with steam.
The effect of both the type of initiator and the extent of the compartmentalization of initiator radicals between the polymer particles on the molecular-weight distributions were analysed by means of a mathematical model.
The formation of structured particles with the targeted core/shell morphology, i.e. liquid cores and polymeric shells, is extremely dependent on the type of RAFT agent used in conjunction with the type of initiator used.
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Based on the optimized procedure, various factors including the type of initiators such as oil soluble initiator, water soluble initiator, redox initiator system, crosslinking agent, functional monomers etc. were systematically studied.
The concentration of the monomer (acrylic acid), reaction temperature and the reaction time (1 and 3 h) are important factors on the grafting degree – especially because our goal was not to use any initiator during the reaction (there are well known procedures for grafting of polymers by using different type of initiators).
The type of initiation, the initiator concentration, the monomer concentration, and the viscosity of the aqueous medium were the subject of variation.
Well-known and less-known initiatives are considered and projects with different types of initiators.
Different experimental recipes were proposed with commercial initiators in order to compare the system performance with two types of initiators: monofunctional and bifunctional peroxides.
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