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This should not be confused with a pure PdIV complex, but the contribution is still strong enough to allow palladium to achieve an octahedral geometry in which the two coordinating BQ carbon atoms occupy two coordination positions.
The dithiolene ligands containing N coordinating atoms present two coordination poles which can selectively bind different metals and act as bridging units in a variety of coordination architectures.
Two coordination polymers, [Zn pda)(bib)]n (1) and [Cd pda 0.5 bib Cl]n (2)].
The use of triazine and aromatic carboxylic acid as mixed chelating ligands in preparing two coordination polymers is described.
The results showed that the topologies are largely dependent on the coordination angle between two coordination groups.
Single-crystal X-ray analysis revealed that the two coordination polymers possess two types of 2D layered structures.
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The DOTA-chelator provides eight coordination sites, which are all coordinated by Sc III), whereas NOTA can only form six coordinative bonds.
AgAg interactions exist in four coordination polymers.
Four coordination patterns are defined for workflow integration.
Those paramagnetic, high-spin, mixed-ligand complexes of Co II) contain six coordination sites.
Figure 2b displays ordered pore structure with the configuration of six coordination pores.
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