dtotal turnover number of cofactor.
Palladium content beyond 3 wt% has no significant effect on the turnover number of phenol hydrogenation.
Thus, a high turnover number of 209 was attained in 0.075 M H2SO4.
The turnover number of H2PtCl6/TiO2 was about two-times larger than that of RhCl3/TiO2.
Nonetheless, the reaction rate would depend on the turnover number of the enzyme.
The overall turnover number of ATP/ADP was calculated to be 36.8, while that of NAD+/NADH was 17.5.
With this method, recycling of the catalyst is feasible; a total turnover number of 1456 was reached.
Furthermore, a quantum efficiency of 6.9% and turnover number of 2210 were achieved by the PEDOT-coated electrode.
TTN generally indicates loss of cofactor due to degradation or incorrect regiochemistry of regeneration, and reaction rate and turnover number of biocatalyst (Zhao and van der Donk 2003).
The turnover number of the immobilized enzyme was estimated to be 65 s–1 which is the same as the catalytic number of the enzyme in solution.
Comparison of both homogeneous and heterogeneous reactions highlighted the interest of the [Ni tmc)]Br2-modified Nafion® electrode that led to a higher stability of the catalyst with a turnover number of 180 and a higher current efficiency.
