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It has a smaller potential tuning rate.
The tuning rate of the device is about 0.3 ns.
Like the CO Stark tuning rate, the metal-CO vibrational Stark tuning rate also increases as CO surface coverage decreases.
The device is a good candidate for integrated optical circuit, the tuning rate of which is about a few microseconds.
In addition, we have found (at 0.25 ML) that the CO Stark tuning rate is similar at different adsorption sites, being only slightly larger at high-coordinated sites.
Stark tuning rates have been calculated at various CO coverages; a linear dependence between the CO Stark tuning rate and the CO surface coverage has been found.
Similar(31)
Particular attention has been focused on the determination of the CO and metal-CO vibrational Stark tuning rates.
CO vibrational Stark tuning rates of 45.58, 47.96, 47.61 and 48.49 cm−1/(V/Å) have been calculated for ontop, bridge, hcp and fcc hollow sites, respectively.
This result is in contradiction with experiments, which reported larger CO Stark tuning rates at high-coordinates sites than at ontop sites.
The general understanding of so-called electrochemical Stark tuning rates, that is, the potential dependence of vibrational frequency of CO adsorbed on Pt(1 1 1), has developed over the past thirty years in terms of two semiempirical models.
Linear relations were found both in acidic and neutral solutions with tuning rates of ca. 50 cm−1 V−1 in the potential region between 0.50 and 0.90 V RHE where the saturated NO adlayers are stable.
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