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This translates to low true capacitance at the CE/electrolyte interface which could imply a better electrocatalytic activity.
Defining the quality factor Q for a parallel circuit by Q = (ωC m)/G m, the true capacitance should be measured for Q ≥ 5 [17].
Then, it has been demonstrated that once the parasitic components are taken into account, it was possible to determine the true capacitance values free from errors.
Considering the MIS structure consisting of a junction capacitance C, a junction conductance G, and a series resistance r, the true capacitance C t could be corrected by measured capacitance C m, measured conductance G m, and frequency f as follows: C t = C m[1 + (G m/ωC m 2], with ω = 2πf [17].
Similar(56)
The true membrane capacitance will therefore correspond to the estimate C e which minimizes the right-hand side of Eq. (6) evaluated in some voltage range where the I V curve is linear (in practice ±1mV from the resting potential).
The true faradic specific capacitance due to redox processes measured at low scan rates increases dramatically when the PPy nanostructure transforms from core-sheath to nanotube.
As shown in the previous section, however, the assumption is not true due to the capacitance change; the haptic force fluctuates even when a constant haptic voltage is applied.
However when the sensing frequency is too high, the measured capacitance can underestimate the true value.
Hence, the measured capacitances deviated from the true ones at high junction conductance.
Furthermore, for the frequency higher than 100 kHz, the capacitance densities deviated from the true ones, which were attributed to the relative resistances of Mg-doped InN films.
The maximum of the capacitance coincides with the p.z.c., but it is true only for this 'symmetric' system.
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com