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Infiltration by a solution of a crosslinker was followed by the UV triggered polymerization of secondary polymeric chains.
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Triethyl amine (NEt3) has already been described to trigger polymerization of HA at 0 °C (Arslan et al. 2004).
Directed by transition metal ions, the self-assembly of the building blocks triggered polymerization to form the corresponding metallo-supramolecular polymers PCzTPY, PSiTPY and PNTPY, respectively.
Examples referring to photochemically triggered polymerizations at the air/water interface provide insights into many of the relevant issues.
Moreover, it was found that the compounds with well-ordered structures of phenol hydroxyl groups and amine structures exhibited relatively weak acceleration on the trigger polymerization of nitrile groups, while higher subsequent polymerization rate, in comparison with the other model compounds, which can be ascribed to their space configuration and the steric hindrance effects.
In particular, different initiators triggering polymerization at different times can be used, thus reducing the possibility of thermal runaway by engineering temperature history and initiator nature/concentrations.
Such a low incidence of EN-actin formationformation suggests that specific conditions are required to trigger polymerization.
Finally, knowing the photophysical reaction which triggers polymerization inhibition, we explored alternative PIs for this efficient lithography technique.
In this assay, horseradish peroxidase (HRP) + hydrogen peroxide (H2O2) + tyramine (TYR -induced gold nanoparTYR -induced agoldgationanoparticleered AuNP signaggregationAuNP aggregation could be triggered through the phenol polymerization of TYR, wasconsidereduced by hydroxyl rasicalsignal HRP-catalyzed H2outputAuNPbeled caggregationT) was used as a couldting antigen to consume H2O2.
The introduction of S2O82− triggers the emulsion polymerization of styrene.
The released target found another molecular beacon to trigger the polymerization cycle, resulting in the multiplication of the reporter Au NPs on the sensor surface.
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