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Toxicity of BDD treated solution was significantly higher than Ti/RuO2 treated solution at the end of the process.
The volume ratio of treated solution and exhausted adsorbent was almost 7000.
Although by-product formation was found, no halogenated by-products were found in the treated solution.
The amounts of residual Al and Fe in treated solution were pH dependant.
One experiment was designed for the effect of oxygen atmosphere in the case of magnetic treated solution in neutral medium.
The acid treated solution was re-treated by electrochemical oxidation (EO) and electro-Fenton (EF) techniques using graphite electrodes.
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In this case, the biodegradability of the treated solutions occurred rapidly.
It was also found that treated solutions presented oxidation-resistant intermediates as final products in all cases.
LC-MS analysis of treated solutions allowed the identification of 25 aromatic and heteroaromatic products and 30 hydroxylated derivatives.
The reduction in toxicity was directly correlated to a decrease in the concentration of 2,4-DCP in the treated solutions, as measured by high-performance liquid chromatography.
The application of ultrafiltration process results in separation of photocatalyst from the treated solutions whereas during nanofiltration and membrane distillation high retention of degradation products was obtained.
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com