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Forbidden transitions proceed slowly compared to the allowed transitions, and the resulting spectral emission lines are relatively weak.
In the high elastic state, λ-relaxation region transitions proceed by segmental motion, with activation energies up to 55 kJ mol−1.
We make no assumptions about short-lived or transient intermediate steps; our key assumptions are that (1) these processes have reached a steady state and (2) upward transitions proceed at a rate proportional to the excitation intensity.
These two analytical methods assume that melting transitions proceed in a two-state manner; that is, intact duplex and unhybridized single strands are dominant, and partially melted duplexes are negligible throughout the melting transition.
Similar(56)
One likely mechanism for this process might include π- to α-helical transitions, proceeding in reversible steps, in which π-hydrogen bonds (i + 5 → i) break and re-form as α-hydrogen bonds (i + 4 → i).
In a statement, Mrs. Clinton said "it is vital that Libya's transition proceed in a spirit of national reconciliation and justice, not retribution or reprisal".
"For the U.S., the priority is that the transition proceeds smoothly, without violence and with a minimum of instability.
At the same time, he has said that he will launch a "diplomatic surge" to ensure that the transition proceeds in an orderly fashion.
The transition proceeds with a conservation of the aggregation number.
The α-to-γ′ phase transition proceeds much slower than the growth of the transcrystalline α-PVDF layer.
For epitaxial MnAs films on GaAs substrate, the transition proceeds continuously over a broad temperature range with coexistence of the two phases.
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CEO of Professional Science Editing for Scientists @ prosciediting.com