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This is as a result of increasing in particle size and shape transition of nanoparticles from spherical particles to triangular nanoplates.
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Thus, we can conclude that the nanoparticle polarization should be formed by several optical intraband transitions of nanoparticle electrons in weak optical fields.
The applied magnetic field during the synthesis of FePt nanoparticles not only significantly improves the nanoparticles' c-axis preferred orientation but also benefits the phase transition of FePt nanoparticles from face-centered cubic to face-centered tetragonal structure during the annealing process.
In cases where the PL energy strongly depends on the size of Si nanoparticles, it arises most likely from band-to-band transition of Si nanoparticles because the bandgap energy is determined by its size due to the quantum confinement effect [1, 2].
In addition, an applied magnetic field during the synthesis of FePt nanoparticles also enhances the chemical ordering parameter S of the 2# and 3# samples and benefits the phase transition of FePt nanoparticles from fcc to fct structure during the annealing process.
Another optical property that can be affected by shape transition of metal nanoparticles is photoemission spectrum.
It clearly indicates the step wise transition of TiO2 nanoparticles while increasing the template concentration from relatively undefined agglomeration.
As it is clearly observed from Fig. 14, there are two groups of photoluminescence peaks located around 400 500 and 550 650 nm which have been enhanced by shape transition of Ag nanoparticles from spherical to triangular.
It is revealed that an applied magnetic field during chemical synthesis not only significantly improves the c-axis preferred orientation but also benefits the phase transition of FePt nanoparticles from fcc to fct structures.
If PL arose from the band-to-band transition of Si nanoparticles, the PL energy would strongly depend on the excitation energy because with an increase in the excitation energy, wider bandgap Si nanoparticles can be excited, leading to PL emission with higher energy.
As shown in Figure 1, the presence of typical excitonic peak and redshifts from 520 to 575 nm with the CdTe precursor undergoing a continuous refluxing process which attributed to 1 s to 1 s electronic transition of the nanoparticles indicates that the size of CdTe QDs gradually increased [19].
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Justyna Jupowicz-Kozak
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