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Moreover, an increase in the fitted mass transfer timescale of each of the single-rate models is coupled with an increase in the associated fraction of instantaneous sorption sites.
The correlation explains many of the variations in the mass transfer timescale encountered when single-rate sorption approaches were utilized to model solute transport in previous miscible displacement studies.
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Several driving mechanisms exist for stable mass transfer with their own characteristic mass transfer timescales.
This provides an unrecognised potential for genetic transfers across timescales of many generations, and a cause of anachronistic evolution.
The model illustrates that the timescale for transfer of energy to the film is typically much smaller than the inertial timescale associated with film bending; in such cases, the film deflection is governed entirely by the impulse delivered to the film and is insensitive to the details of the pressure generated by the laser pulse.
Moreover, we report complementary data from native electron capture dissociation (NECD) 10 of th Cyt c. IMS 5a and NECD 10 experiments previously showed that the native fold of hh Cyt c disintegrates on a ms timescale after transfer into the gas phase as a result of an essentially reversed order of regional protein stability.
33– 35 If the reorientation of E287 occurs on a slower timescale than H transfer (during k−2 and/or k′−2) then these protein dynamics could effectively gate the H radical transfer steps.
An approximate model is obtained after a timescale decomposition and transfer function (Padé) approximations.
And while Romanov is open to the prospect of selling the club, Fedotovas says there is no fixed timescale for a transfer of ownership.
With this new fusion we provide further kinetic evidence for the existence of heme bL– bL electron transfer on a catalytically-relevant timescale.
Finally, one should carefully consider the role of thermal lattice fluctuations that can lead to dynamic modulations of the intermolecular packing and the associated charge transfer integrals on the same timescale as carrier motion.
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