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Ethyl, n-propyl, iso-propyl and n-butyl crotonates were polymerized by group transfer polymerization (GTP) using ketene trialkylsilyl acetals as initiators in the presence of mercury (II) iodide as catalyst and iodotriethylsilane as co-catalyst.
Liu, J. et al. In situ formation of protein-polymer conjugates through reversible addition fragmentation chain transfer polymerization.
He is best known for his discovery of a group transfer polymerization process – a fundamentally new method for polymer production.
However, traditional PAA brushes are synthesized by reversible addition fragmentation chain transfer polymerization.
Amphiphilic star copolymers were synthesized by sequential monomer and cross-linker additions using group transfer polymerization (GTP).
HBPSt-g-PNIPAM was synthesized by grafting PNIPAM from the termini of HBPSt via reversible addition fragmentation transfer polymerization.
Both conjugates were synthesized using RAFT (reversible addition fragmentation chain transfer) polymerization resulting in narrow molecular weight distribution.
Azido terminated pN was synthesized by reversible addition-fragmentation chain transfer polymerization and reacted to Hyal-pa via CuAAC.
Iodo-terminated polystyrene and poly methyl acrylate) (PMA-I) were synthesized by reverse iodine transfer polymerization.
The living PMMA was prepared by the group transfer polymerization of MMA.
The block and random oligomers with narrow polydipersity were prepared by group transfer polymerization.
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