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In all the cases the transfer equilibrium was shifted towards the interface region.
The effects of surface structure and of solution concentration upon the transfer equilibrium constant have been studied.
It has been established that Cu (II) generated in the atom transfer equilibrium is vital in controlling the polymerization.
Although the use of sacrificial initiator would alleviate this problem, by way of generating sufficient concentration of Cu II) to control the atom transfer equilibrium, this would result in the formation of free polymer that will have to be separated from the reaction mixture.
The impact of neighboring evolutionarily conserved polar residues on the protonation state of K279 was studied by examining their effects on the proton transfer equilibrium.
The two most important thermodynamic parameters dictating the character of the titrations are the difference between the intrinsic p Ka values (p KA′A – p KA′B), which determines the internal proton transfer equilibrium, and the coupling (W), which determines the degree of internal buffering.
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Set to tracks from Max Richter's 2002 album, "Memoryhouse," the piece is a fluid, meditative series of encounters between the men that keeps exploring ways of shifting and negotiating weight, testing and transferring equilibrium, using gravity to generate movement rather than — as in ballet — fighting its pull.
Higher solvent polarity can promote the proton-transfer equilibrium and leads to the higher yield [20].
Eventually the partial pressure gradient between the air and blood dissipates and gas transfer stops; equilibrium is then reached, usually before the blood leaves the lungs.
The film mass transfer (FMT), equilibrium (EM), Matzain (1999), and Venkatesan (2004) models were tested against 70 experimental data points (19 sets of initial operating conditions), obtained with four different oils and flow loop facilities.
For the impregnation of one species the following process variables have been considered: Effective coefficient of diffusion of the active species into the pores of the support, external mass transfer coefficient, equilibrium constant of the adsorption desorption process, and maximum concentration of the active sites.
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