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Indeed, as ZrO2 is sputtered immediately after TiN, the O2 plasma will react with the TiN surface to form a TiO x N y layer when the ZrO2 layer is still very thin.
We present a simple algorithm that maps any changes in the configuration of TIN landscape nodes onto a static grid, facilitating the creation of a fixed stratigraphic record of TIN surface change.
For a TiN surface coating of 4 µm, the interface contact temperature was raised to 73.6 °C.
The SEM observation indicates that there was no pinhole on the TiN surface prepared by PBII.
Moreover TiN surface layer facilitated the formation of graphitic microcrystal in the carbon layer.
The XPS results indicate that titanium oxide and titanium oxynitride were present on the TiN surface.
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The as-prepared superhydrophobic tin surfaces also display excellent properties of anticorrosion, self-cleaning, long-term stability and durability.
The influences of magnetic stirring and electrodeposition time on the wetting properties were also investigated to understand the formation mechanism of the superhydrophobic tin surfaces.
The resulting superhydrophobic tin surfaces shows a porous tremella-like morphology and the water drop can fully bounce as a balloon on such a surface, exhibiting excellent non-sticking property.
Pluripotent human mesenchymal stem cells (hMSCs) were exposed to the resulting TiN surfaces in both proliferation and osteoblastic differentiation biomolecular environments.
On the basis of experimental arguments, the state at 1.1 eV was ascribed to the OH-terminated tin oxide surface, the two other states were found to be specific of the interaction of organic matter with the oxide surface.
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