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However, one-dimensional ladder formed by 4,4′-bipy and Cu 4-aba) units in 4 is extended into a three-dimensional arCu 4-abare throunitsnterpenetratinn of the lateral 4-aba arms isto squarextendede adjacent Cu–(4,4′-binto ladders and extensive hydrogen bonding interactions.
The synthesis of MOFs with mesoporosity remains a great challenge because of their tendency to reduce or eliminate porosity through interpenetration or other void-filling means 14 and crystals of mesoporous MOFs tend to disintegrate upon removal of the guest.
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(21) Moreover, the response of the RSVs to nondestructive stresses suggests the presence of a three-dimensional structure formed through the interpenetration of polymer chains and the formation of secondary interactions.
An analogous investigation into the ring-opening polymerization of 1,4-dihydro-2,3-benzodithiine 1,4-dihydro-2,3-benzodithiine 1,4-dihydro-2,3-benzodithiine 1,4-dihydro-2,3-benzodithiinees caffordedto novel catenane topolymers through the interpenetration of multiple faces of the cage.
The fractured polymer samples can be attached through chain diffusion, interpenetration into a crosslinked network, and intermixing/reentanglement.
He establishes this interwoven family network through a rhythmic interpenetration of lines and shapes; the line between the smallest human figure in the lower left center of the composition and the larger figure beside it suggests a literal (physical), as well as a symbolic (emotional) representation of the bond between a child and a parent, probably the mother.
The effect of the surface charge is to reduce the thickness of this layer, eg through the liquid phase interpenetration.
Each rectangular grid undergoes threefold interpenetration resulting a 2D interpenetrated supramolecular framework with hydrophobic small pores.
The structure of 1 contains 2D (4,4) networks showing 2D → 3D parallel interpenetration, whereby adjacent 2D sheets interlock through the apertures defined by the cleft-like Tröger's base ligand, to realise an overall 3D entanglement.
In our previous work, we have investigated the adsorption selectivity of CH4/H2 in three pairs of isoreticular metal-organic frameworks (IRMOFs) with and without interpenetration to study the effect of interpenetration on gas mixture separation through Monte Carlo simulation.
The morphology of a series of hydrogels based on the interpenetration of poly 2-hydroxyethyl acrylate) and poly 2-hydroxyethyl) hacrylatestudied through trandmission electron microscopoly ethyltomic force microscopy, acrylate dynamic–mechasical spectroscopy, DMA.
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