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The phrase "though unexpectedly" is correct and usable in written English.
It can be used to introduce a contrast or an unexpected outcome in a sentence. Example: "She won the competition, though unexpectedly, as many thought her rival would take the prize."
Exact(4)
The costs in the MammaPrint arm are, though, unexpectedly lower [ 51].
The Bayes tree though unexpectedly placed S. purpuratus as a sister to one of the Echinometra clades.
Quantitative RT-PCR confirmed efficient knockdown of p65 in both attached and suspended cells, even though unexpectedly, p65 was also upregulated when MCF10A cells were cultured in suspension.
The solution leads to a set of general, though unexpectedly simple optimization principles, which correct some earlier speculation [ 17] and are useful as first approximations for actual projects.
Similar(56)
The themeless & empty election--though unexpectedly potent in altering the political climate that had existed for so long before it--gave no clue to that.
At present, the resistance movement, though as unexpectedly large as the movement of 1967, is still focused mainly on symptoms, the expanding list of inhumane 1% policies the Republicans (themselves in chaos) are preparing to foist on the nation.
One day he showed up unexpectedly, though.
Unexpectedly, though, the wharf side of the World Financial Center bustled.
Unexpectedly, though, instead of passing through the gold foil, some of the particles bounced back.
Her much-sought-after independence was derailed in 1969, though, when she unexpectedly became pregnant.
Not unexpectedly, though, his first months in the NBA have been mixed.
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Since I tried Ludwig back in 2017, I have been constantly using it in both editing and translation. Ever since, I suggest it to my translators at ProSciEditing.

Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com