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The catalytic mechanism of this transformation proceeds through initial binding of ATP to the purine binding site (P-site) followed by metal mediated cyclization with loss of pyrophosphate.
It is shown that this transformation proceeds with a variable self-strain corresponding to a variable polydomain structure of the martensite phase.
This transformation proceeds by opening of the intermediate cyclopropyl gold(I) carbene in a process mechanistically related to the hydroxy- and alkoxycyclization of 1,6-enynes.
This transformation proceeds with remarkable high Z-selectivity in the final alkenes and the retention of the configuration of diastereomerically pure substrates.
Similar(55)
However, the transformation proceeds very inhomogeneously and results in a mixed microstructure consisting of transformed and untransformed regions.
It is found that the characteristic of the transformation varies as the transformation proceeds.
It has been found that during the cyclic phase transformations the transformation proceeds via the migration of existing austenite ferrite interfaces.
While most features are in agreement with a first-order transformation, the transformation proceeds continuously to lower temperatures, an effect which can be explained by the constraint from the substrate.
It is shown from both simulation and disconnection theory that the primary structural disconnections formed when creating the fcc bcc bicrystal do not move laterally across the boundary as the transformation proceeds.
Examination of the stereochemical outcome revealed that the transformation proceeds with inversion of stereochemistry.
The [112] orientation was chosen to produce two variant formations and in this case, the transformation proceeded over an ascending stress strain curve compared to the nearly plateau response for the [148] case.
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CEO of Professional Science Editing for Scientists @ prosciediting.com