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The 400 MHz NMR spectrum and the ESI mass spectrum of this isolated product were identical to those of reference cyclopamine (a kind gift from Dale R. Gardner, Poisonous Plants Research Lab, Logan, UT).
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All yields refer to the isolated products.
All of the yields refer to the isolated products.
In this research, we used, instead of propargyl bromide, other reagents, such as chloroacetone, and we studied the configuration of the isolated products.
HPLC analysis of the isolated products indicated that the samples were primarily diphosphate but there was some decomposition to the monophosphate.
This gave 7 ac as the sole product in a yield of 94%% isolated product in the same period of time, which confirms that 7 ac is formed by Michael addition without the need for rhodium or copper.
In contrast, the addition of the organolithium 31 to 1 a gave the cyclobutenone 32 as the sole isolated product.
This would consist of physically isolated product-producing cell populations, product capture devices, and other unit operations that function as programmed in place, using unique, orthogonal inputs.
Darwinians at the time treated people as isolated products of competition.
The reaction mixtures and isolated products were characterized using a LC/MS system.
Recently, considerable attention has been focused on exploring the potential antioxidant properties of plant extracts or isolated products of plant origin.
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