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For this catalyst, the thermogravimetric curve seems to indicate a three-stage decomposition.
When the alkenes are hydrogenated over this catalyst, the reaction takes place within the ultramicropores of the carbon.
It has been found that, with this catalyst, the controlling step corresponds to the dissociation of H2 on gold atoms of low coordination.
With this catalyst, the reaction proceeds by a non-ideal bifunctional mechanism resulting from the superposition of a monofunctional acid and a bifunctional metal acid mechanism.
For this catalyst, the maximum oxidation rate was observed at ca. 300°C with the combustion starting at about 250°C.
To understand the kinetic behaviour of the hydrolysis reaction in the presence of this catalyst, the experimental data were fitted to three kinetic models (zero-order, first-order and Langmuir Hinshelwood) using the integral method.
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The unique properties of this catalyst facilitate the synthesis of such compounds.
In turns out that this was just the catalyst the founders were looking for.
When the calcination temperature of Al2O3 was 400 °C, this catalyst showed the highest catalytic activity.
In contrast, testing of this catalyst for the asymmetric epoxidation of chalcone (80) resulted only in the formation of racemic 81.
Furthermore, this catalyst bears the good stability.
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