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To validate our viewpoint, the vapor liquid equilibrium (VLE) data of the two ternary systems: THF (1) + water (2) + 1, 2-propanediol (3) and THF (1) + water (2) + DMSO (3) were measured at 101.32 kPa.
After the resulting solution was maintained at −78 °C for 30 min, a solution of 15 (2.00 mmol, 1.0 equiv) in THF (1 mL) was slowly added for 10 h.
The ansa-metallocene complex (CpCMe2Flu Nd(C3H5)(THF) (1) is an effective single-component catalyst for the production of syndiotactic styrene-rich polymer materials modified by isoprene and/or ethylene.
After cooling to RT, N-methylethylamine (0.38 g, 6.4 mmol) in THF (1 mL) was added.
A solution of LiHMDS (1 m in THF; 1 mL, 1 mmol, 1 equiv) was added dropwise.
After this, a solution of ketone 8 (0.054 g, 0.18 mmol) in THF (1 mL) was added.
Similar(37)
As the ethers, tetrahydrofuran (THF), 1,2-dimethoxyethane, diethoxyethane and 1,3-dioxolane were used.
For the LVS, tetrahydrofuran (THF), 2-methyl-THF, 1,2-dialkoxyethanes and 1,3-dioxolane (DOL) were used.
Nitric acid, sulfuric acid, tetrahydrofuran (THF), 1,4-dioxane and 2,2′-azosiobutyrontrile (AIBN) were provided by Sinopharm Chemical Reagent Co. Ltd. (Shanghai, China).
Special types of water-soluble liquid materials, such as THF, 1,4-dioxane, and t-BuNH2, form sII double hydrates upon reacting with gas guest molecules.
The solvents used were ethylene carbonate (EC), propylene carbonate (PC), 2-methyl-tetrahydrofuran (2MeTHF), THF, 1,2-diethoxyethane and 4-methyl-1,3-dioxolane, LiAsF6 and LiCF3SO3 were used as the solute.
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