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Temperature variations reflect changes in the kinetic energy and thus in the thermodynamic behaviour of vibrating atoms.
The thermodynamic behaviour of a monatomic gas in the ordinary temperature range is extremely simple because it is free from the rotational and vibrational energy components characteristic of polyatomic gases; thus its heat capacity is independent of temperature and molecular (here, atomic) weight, and its entropy (a measure of disorder) depends only on temperature and molecular weight.
Hence, ergodicity is not necessary for thermodynamic behaviour.
Starting with a preliminary suction muffler concept, numerical simulations have been carried out to optimise the thermodynamic behaviour.
A complete theoretical analysis on the thermodynamic behaviour of a HYbrid Compressor and Ejector Refrigeration System HYCERS––is carried out.
Bricmont (2001) investigates the Kac Ring Model and a system of n uncoupled anharmonic oscillators of identical mass, and points out that both systems exhibit thermodynamic behaviour and yet they fail to be ergodic.
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The thermodynamic phase behaviour of blends composed of two random copolymers of polystyrene-co-methyl methacrylate (SMMA) and polystyrene-co-acrylonitrile (SAN) was studied using a modified Flory's equation of state (EOS) theory.
A mechanistic model based on kinetics of gas bubble growth due to solute diffusion in supersaturated oil liquid was formulated and presented to interpret the observed time-dependent non-thermodynamic equilibrium behaviour of pore pressure and volume changes.
Experimental distribution ratios obtained for water, nitric acid and ruthenium were described with a physicochemical model based on the application of the mass action law on each extraction equilibrium and by taking into account deviations from thermodynamic ideal behaviour both in aqueous and organic phase using Mikulin and Sergievskii-Dannus equations.
The thermodynamic and kinetic behaviours of alkali metal ion transfer facilitated by some crown ethers (18-crown-6, dibenzo-18-crown-6, dibenzo-24-crown-8) from water to nitrobenzene were studied by means of cyclic voltammetry and impedance measurement.
These findings are of interest and value to researchers and engineers working on phase equilibrium calculations and/or developing thermodynamic models for phase behaviour.
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