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A semi-analytical solution was obtained for the surface intermediates.
The promoting effect of the additives may be caused by stabilization of the surface intermediates leading to alcohols.
A micro kinetic model, including the surface intermediates, was derived for an In/ZSM-5 catalyst by the NOCH4O2 experiments where the reactant concentrations, space velocity and temperature were varied.
The in situ FT-IR, Raman and UV vis spectroscopic measurements provided molecular level information about the surface intermediates and the surface vanadium oxide species as a function of different conditions.
The reactivity of the catalysts was plotted as a volcano plot against two descriptors; the carbon and oxygen binding energies of all the surface intermediates, reactants and products species.
Using a temperature-programmed online MS system, gas products are directly analyzed at low temperature to understand the reactivity of the surface intermediates on an Au/TiO2 catalyst that exhibits catalytic activity for CO oxidation.
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From TWC to deNOx processes, N2O is the surface intermediate leading to dinitrogen.
Density functional theory calculations for the surface intermediate of this copper-catalyzed process provide mechanistic insight into the effects of the functionalization scheme on surface coverage.
Based on the measurements, SiHx is considered to increase the trichlorosilane consumption efficiency and to decrease the SiCl2 production by increasing the silicon formation rate from the surface intermediate species, SiCl2.
However, the chemical potential of the surface intermediate (µI) consists of two terms, and R Tln(θ i/ θ*), where is invariant for a given catalyst and R Tln(θ i/ θ*) is the coverage-dependent term.
With this respect the rates of diethyl ether (DEE) and ethylene formation in ethanol dehydration along with the quantification of the surface-intermediates (ethanol monomer and dimer) were simultaneously assessed under different reaction conditions in H-MFI zeolite.
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