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The opposite configuration is called a tricycle gear, with a single nose wheel and two main wheels farther back.
(Also welcome are sugars of the opposite configuration).
The opposite configuration causes a main vortex to be succeeded by a wake where vortex structures are not clearly defined.
Compounds 98 101 are the monoepoxylignan glucosides with the 9-O-7' framework, while -lariciresinol (101) occupied the opposite configuration compared with others [5, 7, 15, 25, 26].
CO2-based stereocomplexed polycarbonates derived from the intermolecularly interlocked interaction between the enantiopure polymers with the opposite configuration exhibit high crystallinity, excellent thermal and mechanical stabilities.
In addition, when the feedforward input is regular (spiking or bursting) and asynchronous, the output is regular if recurrent synapses are more distal than feedforward ones, and irregular in the opposite configuration.
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The opposite configurations allow enantiomers to be discriminated by their enantiospecific interactions with another chiral molecule in membranes.
The crystallization behavior of the stereoblock copolymer of substituted and non-substituted poly(lactide)s, i.e., poly d-2-hydroxybutyrate) and poly d-2-hydroxybutyrateaving the opoly d-2-hydroxybutyrateP(D-2HB)-b-PLLandand the reference block copoly l-lactidey(d-2-hydroxybutyrate) and poly l-lactide) chains withavingidentheal coppositetions [P(D-2HB)-b-PDLA] was investigated.
However, the enantiomeric excesses of the products, of opposite configuration compared to the products formed using Novozyme 435, were lower than for the CAL-B-catalyzed reactions (0 37 % ee).
Compounds 76 and 77, isolated from the root of S. officinalis, are the diastereoisomers with opposite configuration at C-5 [29].
An intriguing outcome of this report is that the (S, S -bis(oxazoline)-Ph-Cu(II) complex provided the fluorination product 10c with oppoS -bisoxazoline -Ph-Cu IIt oxazoline -Ph-Cu II oxazoline -Ph-Cu IIline)-Ph-Ni(II), both with high enantioselecomplex.
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