Sentence examples for the mode of coordination from inspiring English sources

Evaluating the mode of coordination in metal carboxylate systems involves use of the magnitude of separation, ∆ν cm−1, between νa(COO) (carboxyl asymmetric) and νs(COO−) (carboxyl symmetric) stretching vibration bands [60, 63, 64, 66].

The mode of coordination of the 8-hydroxyquinolate ligand in the previously reported Pb II) complexes, namely [Pb2 8-Quin)2(NO3)2(MeOH)] [Pb2 8-Quinb4(8-Quin)4(Tp)2 NO3 2]n[37] (where MeOH = Methanol, DMF = Dimethyl Formamide)is similar to the one found in complexes (1) and (2) (Figure 2).

The modes of coordination of cis-[Pd dpa Cl2] and cis-[Pd dpa Cl2O)2]2+ in the reandions with the non-acis-[Pd dpaeptides and the total stericis-[Pd dpan of tH2O 2]2olytic reaction between cis-[Pd(dpa)(H2O)2]2+ and MeCOHin-Gly can be atheibuted to the stereactionsof the palladium(II) complex.

UV Vis and EPR spectroscopy confirmed this mode of coordination.

A structure of human CDO which was anaerobically co-crystallized with cysteine shows that cysteine [53] is coordinated to the Fe(II) center via its sulfur and amino group supporting the mode of substrate coordination as initially proposed by McCoy and coworkers (Fig. 8B) [52].

Chemical communication is the predominant mode of coordination in insect societies and as such is essential for insect eusociality [ 3].

While results from EXAFS spectroscopy suggested that coordination of cysteine via its carboxy-moiety was the most likely mode of coordination [49], MCD spectroscopy of the cysteine-coordinated complexes revealed near UV transition bands, which were red-shifted for the seleno-cysteine-bound analogue, supporting direct coordination of the thiol-group to the Fe(II) cofactor.

The resulting dimeric complex demonstrates a new mode of coordination of the ligand PaPy3H.

In offering a measure of coordination, Visser seeks to allow for variation in the extent of coordination within a particular mode of coordination.

The differences in the observed binding trends of 2 and 3 are likely attributed to the different modes of coordination that these receptors display toward the same guests.

Indeed, its proponents often suggest that, in many circumstances, networks offer a mode of coordination superior to that of both hierarchies and markets.