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The embedded gold particles will further enhance such multi-reflection, by increasing the intensity of reflection.
α m, the intensity of reflection of each bright point, has an statistical model based on the RCS models which is discussed in several literatures [8].
The structure factor contributing to the intensity of reflection from a single domain can be expressed as, where collects the contributions from the Thomson and real anomalous scattering factors of the j atoms at positions in the unit cell, and collects the anomalous imaginary scattering factors.
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The X-ray analysis shows a strict analogy of this orthorhombic phase with the β phase of s-PS, also as for the occurrence of two limit ordered and disordered modifications, which differ for the intensity of reflections characterized by h + k = 2n + 1.
The intensity of reflections appeared to be decreased for TSP as compared to TS due to inclusion of amorphous SiO2.
The program APEX[ 21] was used for collecting frames of data, indexing reflections, and determination of lattice parameters, SAINT[ 21] for integration of the intensity of reflections and scaling, and SADABS[ 22] for absorption correction.
As expected from the crystallite orientations observed by SEM, the data show a clear suppression of the intensity of reflections strongly associated with the c-axis; this was modeled via a preferred orientation fraction of 0.605 2) in the 110 direction.
More importantly, severe preferred orientation suppresses the intensities of reflections for particular directions: the information in the powder pattern is not merely redistributed, it is irretrievably lost.
In principle, on a four-circle diffractometer equipped with a point detector it is possible to measure the intensities of reflections h and at setting angles (2θ, ω, χ and ϕ) and (−2θ, −ω, χ and ϕ) (Le Page et al., 1990 ▶).
It can be clearly seen, when the intensity of this reflection has reached its maximum, that also the characteristic (11) and (20) reflections are observed (Figure 7).
The maximum wavelength of the selective reflection of the cholesteric phase λmax is shifted to the shorter wavelength direction and the selectivity and the intensity of the reflection are decreased after the AA polymerization.
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