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An equation for the entropy of fusion for arbitrary crystallinity is also derived.
Upon reheating, the reverse transformation, i.e. the strong-to-fragile transition, is observed with an entropy change of 0.19 J/ g-atom K), which is 2.4% of the entropy of fusion.
We will demonstrate that kinetic fragility of a glass-forming liquid is quantitatively related to ΔSf/(Tm − TK), where ΔSf is the entropy of fusion, Tm the melting point, and TK the Kauzmann temperature of a glass-forming liquid.
(34) In fact, the melting point has been directly correlated to the Log of solubility, although assumptions pertaining to the entropy of fusion had to be drawn.
Since melting point is a thermodynamic process where the free energy of transition is equal to zero, the value is determined by the ratio of change in the enthalpy of fusion over the change in the entropy of fusion.
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The entropies of fusion ΔSF of B-PE and linear polyethylene (L-PE) at pressures up to 200 MPa have been determined based on the Clausius-Clapeyron equation and P-V-T data by O. Olabisi and R. Simha (Macromolecules, 1975, 8, 206), and ΔSF for B-PE is much smaller than for L-PE.
The lower entropy of fusion (ΔSf) of copolymers indicates that they are less mobile in the molten state.
The melting points, the enthalpy and entropy of fusion were estimated.
The enthalpy and entropy of fusion of the perfect crystal up to 300 MPa determined through the Clapeyron equation remained more or less similar up to 200 MPa but increased significantly at 300 MPa.
Interfacial energies in binary metallic systems were estimated from a few bulk thermodynamic properties, i.e., melting temperature, entropy of fusion, and the critical temperature of the liquid phase.
This contribution reviews the relationships between thermophysical properties of glass-forming alloys: glass transition, specific heat, entropy of fusion, fragility indexes, using recent models for ranking undercooled liquids and glasses.
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