Sentence examples for the elementary rate from inspiring English sources

The expression of the kinetic current as a function of chlorine and H+ concentration was obtained by solving the elementary rate equations of the kinetic mechanism.

Compartment modeling of the product responses from the 13CO and D2 pulse inputs allowed determination of residence times of adsorbed intermediates, surface coverages of adsorbed intermediates, and the elementary rate constants for acyl hydrogenation and CO insertion.

Analyzing the stationary current potential curves with an original simplified reaction scheme of the dissolution passivation of titanium, we have determined the partial reaction orders of the elementary rate determining steps of the mechanism.

Finally, the elementary rate constants extracted from our analyses should provide a reference frame for future computational studies aiming to fully describe the molecular trajectory of a transcribing polymerase.

A more accurate treatment is to use the elementary rate constant in the elongation pathway directly connected to pausing, which is the net rate constant for forward translocation, k 1 net: (11) ρ pause = k b 1 k b 1 + k 1 net = k b 1 k b 1 + [ NTP ] k − 1 (k − 2 + k 3 ) k 2 k 3 + [ NTP ] ⋅ k 1 where kb1 is the rate constant of entering the 1-bp backtracked pausing state.

The algebraic relations among the elementary rates, which describe the manifold, are discussed along with a classification of the unknowns in three classes: i) CSP radicals; ii) trace; and, iii) major species.

Unfortunately, even when in vivo kinetic data is available, it is often in the form of aggregated rate laws (ARL) that do not specify the required elementary rate constants corresponding to mass-action rate laws (MRL).

These explicit simulations require however the direct elementary rate constants and enzyme intermediates that distinguish MRL modelling from ARL modelling.

The MASS-Toolbox focuses on the creation of elementary rate laws and automatically derives pseudo-elementary rate constants with their units.

The stoichiometric coefficients are constant and are connected to the non "steady-state" species, while the related rates involve the slow elementary rates only.

The kinetic model yields satisfactory comparison with these experimental data, and suggests that the reactions involving excited HCl v) species and energy branching are not of substantial significance in combustion situations, and that the use of accurate elementary rate constants is instead crucial to the accuracy of the reaction mechanism.