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the delocalisation
noun
Alternative spelling of delocalization
Exact(4)
In all cases (excluding 4 in DMSO-d6), two separated broadened signals belonging to the 2 × NHaHb arrangement were observed, probably due to the delocalisation of the positive charge throughout the amidinium group.
We postulate that, analogous to the process that occurs in HGPS cells, the build-up of progerin in the nuclear lamina in normal cells contributes to the delocalisation of heterochromatin clusters away from the nuclear periphery, thereby contributing to the large scale-genome decondensation to allow genomic reorganization.
Treatment of T-lymphocytes with PUFAs resulted in the delocalisation of raft-anchored signalling proteins such as LAT [117].
Probably, photo-generation of ROS represents a signal in the delocalisation and insertion of Bax on the OMM.
Similar(56)
For the radical monocations A+ and C+ the spin delocalisation on the central phenylene moiety was confirmed both experimentally and by theoretical calculations.
Thus, this is the first demonstration that we can engineer the defects in ta-C by increasing the electron delocalisation whilst maintaining the high sp3 and optical gap of the material.
Comparison with δ-AgxV2O5 and ε-CuxV2O5 refined structure allows to define crystal chemistry parameters governing the ionic delocalisation and give clues to predict from structural consideration the expected electrical behaviour with the aim to make possible a structural design to enhance guest species reactivity.
We briefly discuss the models used in RPES data analysis to extract the time scale of the excited charge delocalisation and the spatial correlation of core, valence occupied and unoccupied molecular states.
Substitutions on the cyclopentadienyl rings of rhodocenes and rhodocenium salts produce compounds of higher stability as they allow for the increased delocalisation of positive charge or electron density whilst also providing steric hindrance against other species approaching the metal centre.
To exclude the possibility that the timing of Alp4 GFP delocalisation reflects the minimum duration required for heat inactivation of the Pcp1-15 mutant protein, half of the initial culture was incubated at 27°C for a further 40 min during G2 phase, followed by a shift up to 36°C.
The extension of the π-electron delocalisation from one repeating polymer unit to another which depends on the details of the polymer structure determines the properties of the polymer, including the optical non-linearities and sometimes the increased electrical conductivity [1].
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