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The results from the quantum mechanical calculations were then used to determine the rate constants for each elementary step, the overall reaction yields and the corresponding residence time.
The system under consideration is simulated by a unit cell model, and analytical expressions for the flow field and the corresponding residence time distribution under various conditions are derived.
This technique allowed a conversion profile to be established over the corresponding residence time comparable with the results obtained in the laboratory-scale batch reactor and the final GC measurements.
Numerical flow simulations on sufficiently fine computational meshes are performed for different configurations in order to characterize the inflow rate into the aneurysm and the corresponding residence time in the aneurysm sac.
The model takes into consideration of two distribution functions of random surface elements, one with respect to their point of origin and the other related to the corresponding residence time on the membrane surface.
At the temperature of 550 °C and the pressure of 30 atm, CO conversion and CH4 selectivity can remain above 98% and 92%, respectively, at a high GHSV of 71,000 h−1, where the corresponding residence time is only about 50 ms.
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When the flux of the aqueous phase was 45 mL/min with a corresponding residence time of 0.027 s, an extraction efficiency of 98.9% was achieved.
The corresponding gas residence time ranged from 0.5 to 2.0 s.
Both independent approaches were developed in terms of random-trap or valley model where the disorder of energy landscape is exponentially distributed while the corresponding mean residence times in traps obey the power-law.
Using a geographic information system and latitude/longitude coordinate data, TB cases were geocoded to the corresponding block group of residence.
Figure 8 shows the corresponding ratio between arrival and residence probability in the same cell.
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