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Preliminary studies to adjust the configuration about the ring fusion, expected to be an activation step, are discussed.
Single crystal X-ray structural analysis of compound 17 evidenced that the configuration about CN double bond is syn to C-5 carbon (E-form).
Docking studies of 3′ (i.e. original 3 less one chloride) with Cathepsin B reveals a change in the configuration about the vinyl CC bond, i.e. to E from Z (crystal structure).
The proposal in [28] uses a data repository to store the configuration about available hardware and virtual resources which can be accessed using service oriented infrastructure (SOI).
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Talking movies with him is a treat, the conversation leaping from obscurities such as the 1980 asylum-set psychological thriller The Ninth Configuration (about which we discovered a shared obsession when we first met in 2002) to such detective classics as The Big Sleep and The Long Goodbye, both of which cast long shadows over his latest work, Inherent Vice.
The anomeric configuration about αGlcN(1→P←1)βAra4N linkage was confirmed by the corresponding coupling constants JH1,H2=3.3 and JH1,P=7.1 Hz for α- D- gluco- and JH1,H2=3.5 and JH1,P=7.4 Hz for β- l- arabino-anomers, respectively.
Furthermore, because of the change in configuration about the C-4′ hydroxyl group in dTDP-3 N-methylamino-3,6-dideoxygalactose, steric hindrance occurs between it and Cδ1 of Ile 212 (3.2 Å).
In-plane bending tests in the three-point configuration about both the major and minor axes were conducted.
We found that the calculated Curie temperature of the configuration H@Si1 is about 300 K, which is ideal in practical applications in spintronics.
This structure shows that the tripodal phosphane adopts a mer configuration about the rhenium center, with the central phosphorus atom trans to a carbonyl ligand and the terminal phosphorus atoms of the ligand 5 b trans to each other.
Both conformers prefer enol form in the solid state, adopting E configuration about the CN double bond.
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