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A series of copolymeric models were synthesized to make the complete assignment of all the signals appearing in the spectrum of the tetrapolymer.
The glycolipid 1-O-palmitoyl-2-O-stearidonoyl-3-O-β-D-galactopyranosylglycerol (4) was obtained from the brown alga Sargassum incisifolium and for the first time, we report the complete assignment of its 1H NMR and 13C NMR data.
The complete assignment of spectra recorded by us in the present measurements is presented in Table 1.
This was confirmed by the complete assignment of CXCL12γ residues, but K1, E73 and K84 (Fig. 1B).
The complete assignment of the backbone amide resonances of both proteins [11], [12] allows for a residue-specific analysis of the proton exchange rates (Fig. S7, S8 and Table S1).
The complete assignment is presented in Table 1.
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The complete assignments of the vibrational spectra (IR&Raman) were made with the aid of calculated spectra both in gaseous and aqueous phases.
The complete assignments of NMR data are displayed in Tables 2.
To encourage completion of the LBLs, students received credit worth 1% of the total grade for uploading the completed assignment and 0.25% for completing an online quiz covering the material, before the associated class.
The completed assignments of the 1H-NMR spectra in CDCl3 are shown in Fig. 2a.
The more complete assignments of the connection domain included with the present study provide further substantiation of this hypothesis.
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