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The synthesized SSTM has a high terminal functionality and a narrow molecular weight distribution.
The oligomers with phenolic endgroups were subsequently reacted with ethylene carbonate to obtain aliphatic hydroxyethyl terminal functionality.
Electrochemical modification of carbon electrodes by aryl groups bearing a phosphonate terminal functionality was carried out by both electrochemical reduction of diazonium ions (diazobenzylphosphonic acid) and electrochemical oxidation of an amine (aminobenzylphosphonic acid).
The monolayer produced by self-assembly allows tremendous flexibility with respect to several applications depending upon their terminal functionality (hydrophilic or hydrophobic control) or by varying the chain length (distance control).
Thermal properties and viscosities have been investigated in relation to molar mass, backbone structure and terminal functionality; comparisons are made with related saturated and unsaturated systems, and with polymers containing terminal ionic functionalities, formed by alkylation, protonation, or coordination with Cu II), Ni II) and Fe III) chlorides.
Three generations of dendritic-linear copoly arylene ether)s containing aryl sulfide and aryl sulfone groups, and aryl fluoride terminal functionality, have been synthesized using the divergent approach and an activation/condensation sequence that involves oxidation of 4-fluorophenylthio groups and the displacement of the activated halide moiety by a phenolate ion.
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With the lack of high sequence conservation of the C-terminal end with other species, it is difficult to determine the importance or functionality of this domain.
Terminal functionalities provide a platform for conjugation of the drug and targeting moieties.
The chemistry of the core and the terminal functionalities can be tailored according to the specific application.
As an ideal macromolecule, dendrimers have attracted considerable attention because of their unique properties, including their three 3D architecture, monodispersity, highly branched macromolecular characteristics, and tunable terminal functionalities.
The influence of the acetoxy and hydroxyl terminal functionalities in the side groups on the electrochemical properties of these polyalkylthiophenes was studied by cyclic voltammetry and in situ FTIR spectroelectrochemistry.
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