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Exact(10)
A tentative structure of the HQ-PAA adsorbent/Cu2+ complex at pH of 5.4 is pictured in Fig. 11.
For substituted indazoles and related compounds, a purification of such a metabolite to perform structure elucidation should not be necessary as already the information gained from the UV spectrum by a DAD detector should be sufficient to assign a tentative structure.
"He has always thought of a novel, before it has taken on its first, tentative structure, as a scene on this dark plain, the characters standing around a small fire which warmly etches the edges of their faces," Williams writes of his main character, Aaron Benham, a middle-aged novelist and professor.
Its tentative structure was proposed on the basis of its F NMR and 2D F F COSY NMR spectra.
From mass spectrometric analysis, the molecular formula of Mc-NCC-26 was deduced as C34H40N4O10, providing the basis for a tentative structure assignment.
Therefore, absorption spectra may be used for tentative structure elucidation by comparison with the spectra of compound with definitive molecular structure.
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Tentative structure-property relationships for blend compatibility and the nature of the interactions leading to miscibility are discussed.
Tentative structures for all the impurities were assigned based on m/z values from LC-MS/MS analysis.
Presently, the only practicable road is the direct way, that is to compare experimental data to calculations from tentative structures.
If no reference spectra were available, identification was performed based on the mass-spectral fragmentation, in such cases for some compounds only tentative structures were proposed.
This analysis, which is based on homology modelling, revealed a surprisingly well conserved tentative 3D structure of the Arabidopsis MDL proteins in comparison to HsMIF, despite the limited similarity of these proteins at the level of the primary amino acid sequence (ca. 30% identity – see above).
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