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A three-parameter relationship describing both linear and curve temperature programmes is derived adapting a model previously used in literature to describe concentration gradients in liquid chromatography with binary eluents.
All three laboratories use GC methods with Electron Capture Detectors (ECD) but with different columns and temperature programmes.
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This pretreatment was monitored by temperature programme reduction.
Open image in new window Fig. 2 Typical temperature programme oxidation profile [5, 6].
The set temperature programme was 323 K/3 min-temperature ramp of 283 K/min to 503 K with N2 as carrier gas.
The temperature programme for the microwave oven was set to increase to 150 °C during 5 min, this temperature was held for 30 min and cooled for 15 min.
A helium carrier gas was used with a temperature programme set at 270°C – 290°C at a rate of 4°C min-1 with a 20 min hold.
The new non-linear temperature programme that is required is adopted for supply and return temperatures, which allows greater temperature cooling and smaller flow rates.
Both combinations are incorporated in the same oven, using the same temperature programme, and are fed using a 50 50 column-entrance-split.
The temperature programme started at 60°C with 1 min holding time, then increased 7°C/min up to 100°C, followed by 10°C/min increase up to final temperature 200°C, where the temperature was kept for 4 min.
In order to obtain nanocomposite architecture membrane via pore plugging hydrothermal synthesis, the sealed autoclave was subjected to hydrothermal synthesis with interruption at 413 K using the temperature programme described in Daramola et al. (2015).
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