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Proper targeting of reinitiation by Sarkosyl relies on the timing of addition (after de novo PIC assembly but before reinitiation in synchronized reactions).
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Furthermore, SWITCH synchronizes labeling reactions to improve probe penetration depth and uniformity of staining.
Polybenzoxazine (PBa) was successfully hybridized with polysiloxanes by synchronizing two reactions; ring-opening polymerization of benzoxazine (Ba) and sol gel process of diethoxysilanes.
Many protein structures contain tunnels to facilitate efficient migration of intermediates and gates to synchronize chemical reactions.
A Pd/Au ratio dependent N-alkylation activity was observed over PdAu@MIL-100(Fe), implying the possibility of synchronizing the reaction rates of two consecutive steps in the N-alkylation reaction, i.e., photocatalytic alcohol-to-aldehyde dehydrogenation and imines hydrogenation, to optimize the whole reaction.
The reaction is synchronized, or synchronous, in that entry of the nucleophile and departure of the leaving group occur simultaneously.
This work also demonstrates that the reaction rates of different catalytic steps in a cascade/tandem reaction can be synchronized for an efficient overall reaction via a rational design of the multifunctional catalysts.
In addition, the composition in the bulk gas phase is synchronized with the dynamic reaction events occurring on the surface.
By preassembling the DNAP-SSB-DNA complex, we bypass the slow enzyme binding steps and synchronize the unwinding reactions.
In the case of ExChange, there are more constraints since two trans-splicing reactions must be synchronized at both edges of the targeted exon.
However, as aggregation is a stochastic process, molecules will not synchronize during the reaction and, as a result, the reaction mixture will be highly complex and composed of several species at any given time.
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