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Different sweep cycle (charge capacity) had great impact on the morphology and electrocatalytic activity of CoS films.
It is found that, for materials having high resistivity against corrosion, the value of polarization resistance is largely dependent on the sweep rate or the period of sweep cycle.
The switching behavior for the second sweep cycle is shown in Figure 2b.
The device switches from a low-resistance to a high-resistance state, followed by hysteresis in the first sweep cycle.
The devices exhibit a low-resistance state in the first sweep cycle and irreversibly switch to a high-resistance state at 0.8 to 1.2 V bias.
A complete scan through all 160 frequencies takes 1.26 s, and the basic sweep cycle is repeated once every 7.54 s.
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It can be seen that the memory margin keeps beyond 14 times during cycling, and the cell shows little degradation after 100 repeated sweep cycles.
We had done 200 sweep cycles for five times which lasted for about 15 h.
Figure 2 Transport characteristics in the first and second sweep cycles.
c DC sweep cycles without external current compliance of the HfO2 device after nitridation treatment.
The catalytic current behaved similar except for a little decrease in each 200 sweep cycles.
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