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This is because the desorption of inhibitor takes place from the surface of the mild steel.
The corrosion product over the surface of the mild steel in sulphuric acid solution is shown in Fig. 13a.
This increasing inhibition efficiency is attributed to the formation of a protective layer on the surface of the mild steel.
Thermodynamic parameters were computed by evaluating the proper adsorption isotherm model fit for the adsorption of the inhibitor on the surface of the mild steel.
The nature of protective film formed on the surface of the mild steel was confirmed by FT-IR, XRD and SEM techniques.
It could be observed from Fig. 14a that the surface of the mild steel was strongly damaged in the absence of inhibitors due to metal dissolution in acid solution.
Similar(50)
The calculated ΔG ads values are within −40 and −20 kJ/mol, indicating that the adsorption mechanism of 2-chloro-3-formyl quinoline on surfaces of the mild steel in 1 M HCl solution at 303 333 K temperatures was a combination of both physisorption and chemisorption [21, 22].
The surface conditions of the mild steel base plate were 'as-turned' and 'as-ground'.
Surface morphology of the mild steel specimen by FTIR spectroscopy proved the formation of polymer film.
The surface analyses of the mild steel specimens after treatment with 1M HCl in the absence and presence of PVAP were carried out to confirm the adsorption of the polymer composite on the mild steel specimens.
The corrosion rate determination, pH of the end experimental solution and surface morphology of the mild steel specimens under the influence of different AC current densities were studied.
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