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The CV matrix for the clustered distribution clearly shows the surface of the cluster (distribution 5 row 4, column C).
The transfer of charge from the Be atom to its neighboring O atoms in the surface of the cluster indicates the ionic character of the BeO bond, so that BeO bonds are polarized.
Hence, in the thermodynamic limit the island will only form once the (surface of the) cluster is saturated with carbon, and the island will spontaneously form a SWCNT at the chemical potentials required to create the island.
Conformational analysis of 1,3-dithiol ligands using density functional theory (DFT) reveals that they can cap on gold clusters through 1,2-capping mode, in which the two sulfur atoms of the dithiol bind covalently with two adjacent gold atoms on the surface of the cluster.
This reduction is explained by the fact that when particles are clustered in densely populated particle clusters, the transfer of oxygen to the particles in the centre of the clusters is reduced since the oxygen is consumed by the particles closer to the external surface of the cluster.
The surface of the cluster may also influence some of the material properties, such as chirality [18, 19].
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SEM images show that growth occurs on the surface of the clusters at the initial stage; as they grow larger, the clusters converge to form a continuous coating, which is actually stacking of cobalt clusters.
This indicates some ordering of the enzyme molecules on the surface of the clusters.
C60 molecules located at the surface of the clusters were oxidised.
It is supposed that oxygen atoms are bonded to C60 molecules at the surface of the clusters.
It is inferred that oxidised C60 molecules located at the surface of the clusters may have an important role for the reinforcement of the clusters.
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com