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Butane isomerization over sulfated-zirconia can be viewed as being a surface chain reaction comprising initiation, propagation, and termination steps.
In addition, Wang et al. investigated the surface dynamics of ultrathin poly (tert-butyl acrylate) (PtBuA) films and observed the variation of surface chain mobility with film thickness changing by atomic force microscopic adhesion measurement (AFMAM) [20].
Changes in the surface chain structure and the critical surface tension of poly trimethylene terephthalate) (PTT) film under uniaxial drawing were examined by polarized attenuated total reflection infrared (ATR-IR) spectroscopy and contact angle measurement.
From the ATR-IR spectra, it was also realized that the surface chain structure changes with the draw ratio, showing a remarkable increase in the surface crystallinity at the draw ratio between two and three.
TNF-α stimulation remarkably augmented the ∼45 KDa intracellular and 60 65 KDa (referred to be as surface chain) [27] FcεRI-α protein compared to unstimulated B/TSM cells (Figure 2B).
17, 30 As expected, the grafted surface chain density increased with longer coating durations and higher peptoid concentration.
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This demonstrated the strong templating power of our hard polymer microspheres, which counteract the surface chain-forming force caused by the magneto-static energy of ferromagnetic particles.
As endoglucanases act on the surface chains, their activity is not severely affected by fraction of chain ends; however, degree of crystallinity plays an important role in deciding their performance.
After this treatment, Tgs decreased by approximately 15 K in comparison with the intact film due to degradation of surface chains.
In addition, if the enzymes work ablatively on cellulose microfibril surfaces, consuming the less ordered surface layers of cellulose, then internal ordered cellulose chains will become surface chains with decreased order, so that conversion of 'amorphous cellulose' results in production of more 'amorphous cellulose' and a further decrease in cellulose CI.
In addition, the enhanced enzymatic digestibility of cellulose III was reported to be related to the "amorphous-like" nature of its surface chains [ 12].> According to the integrated experimental results (Table 3), the most digestible enzymatic hydrolysis allomorph was amorphous cellulose, followed by cellulose III, cellulose II, cellulose Iα, and cellulose Iβ.
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