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The ceria and titania supports contain a substantial number of metal cations that are not fully oxidized under WGS reaction conditions and may participate directly in the dissociation of water and other important steps of the catalytic process.
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for all with supports contained in.
Open image in new window Fig. 2 a XRD patterns of supports containing La additive.
For convenience of discussion, these are divided into Al2O3 containing mixed oxide supports, TiO2 containing mixed oxide supports, ZrO2 containing mixed oxide supports and other mixed oxide supports containing all the rest.
The production yield was modified for all types of PP supports, containing respectively 0, 0.35 and 0.75% of iron.
Using this method, the highest surface acidity was found on the mixed oxide supports containing 80 wt.-% Nb2O5.
Supported LaCoO3 perovskites with 10 wt.% loading were prepared by impregnation of different supports containing ceria with a solution of La and Co nitrates and citric acid.
High selectivity to butenes was obtained with the catalysts prepared over supports containing alkyl chains, while over-hydrogenation to butane took place over oxygen-containing functional groups.
Iron-modified ceria supports containing different molar percentages of Fe (0%, 10%, 25%, and 50%) were synthesized by thermal decomposition of the metal propionates.
Phosphorus-modified Al2O3 supports containing different P content were prepared to control the acidity of Ni-impregnated catalysts for application in the dry reforming of methane (DRM).
Alumina titania supports containing 5 50 wt.% of TiO2 were prepared by coprecipitation method using inorganic precursors (sodium aluminate and titanium chloride).
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