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Substantial broadening of the diffraction maxima observed at the XRD pattern of La0.5Sm0.5FeO3@1073 sample clearly indicates the nanoscale particle size of the as-obtained product.
The hindering of the segmental dynamics, demonstrated by the strong high-temperature shift of the α mode, is accompanied by a substantial broadening of both the dielectric and calorimetric signals compared to the bulk phase.
The substantial broadening of the series of bonds by substitution of Fe3+ by Al3+ in other amphiboles on, the smaller six-fold coordinated Fe3+ cations which gets generally concentrated in M2 sites studied (Wilkens 1970; Hawthorne 1983; Skogby and Annersten 1985).
This period also saw a substantial broadening of the remedies available in the common law.
Second, fast relaxation rates in large complexes lead to substantial broadening of the NMR signals.
In December 2005 the Board of the GAVI Alliance opened a new 'window' for HSS initiatives, marking a substantial broadening of the scope of its funding [ 30].
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Additionally, PRE measurements under complete denaturation conditions using both high urea and NaCl concentrations were not possible because of substantial viscosity effects (and thus substantially broadened NMR signals).
The lack of observable NMR signals for the four aromatic residues (F164Y165H166Y167) of IsdBN1 likely results from substantial line broadening in the NMR spectrum which is most likely due to chemical exchange on an intermediate (ms) time scale, reflecting the intrinsic flexibility of L2 residues in the unbound solution state of IsdBN1, similar to its homologue IsdHN1.
c The related nano-diffraction patterns showing substantial peak broadening after the exposure to H2O vapor.
Substantial peak broadening of both powders has been observed, indicating a reduction in crystallite size.
Finally, our results suggest that for stoichiometric H2 air mixtures, any substantial flame broadening by the action of turbulence cannot be expected in all subsonic regimes.
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