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Knowledge about such changes can generally be deduced from knowledge of the stereochemistry (three-dimensional structures) of the starting materials, intermediates, and final products (provided these are obtained under kinetic control).
On the contrary, oxidative desulfurization of cyclic thiocarbonates with a CS bond took place to provide the corresponding gem-difluorinated product and/or carbonyl compounds depending on the molecular structures of the starting thiocarbonates.
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This strength depended on the structure of the starting polymers which functioned as a template.
The average structure of the starting material determined by neutron powder diffraction confirmed partial ordering of Mn and Ni cations on the octahedral sites in the spinel structure.
It was found that the functionalization process and the inclusion of the vitamin on the pores do not modify the mesoporous structure of the starting material.
The mass loss profiles and bulk properties of the resulting scaffolds are easily tailored by modifying the structure of the starting macromers.
However, cubic SnP2O7 cycled significantly better than its layered polymorph, which shows that the structure of the starting material is also of great importance.
Whether polymerization, double Michael addition or no reaction occurred, depended greatly on the pKa and on the structure of the starting anion.
Results reveal that differences in the inner structure of the starting glassy material induce different crystallization rates from the glassy amorphous state.
The proposed model and experimental results imply that the structure of the starting thermodynamically stable AgI complexes, used for the first time as a precursor solution, affects the final particle structure.
The pore structure in the carbons was found to a large extent to be similar to the porous structure of the starting sulfonated resin material, however, the metal form was found to impact on the micropore structure of the resulting carbons.
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