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Graphical abstract The strategic structures of the products (7a g).

Fig. 1 The strategic structures of the products (7a g).

The crystal structures of the products are investigated by XRD.

The structures of the products were confirmed via elemental analyses and spectral data.

The structures of the products were confirmed using NMR (1H and 13C), IR and elemental analyses.

X-ray crystal structures of the products [ bpaAc Gly OEt NiCl2] (2), [ bpaAc Gly OEt CuCl]2[(H2O)CuCl3]Cl·3H2O (32[(H2O)CuCl3]Cl), and [ bpaAc Gly OEt ZnCl]2[ZnCl4] (42[ZnCl4]) were obtained.

The structures of the products were deduced from their IR, 1H NMR, and 13C NMR spectroscopy.

The shapes and structures of the products were characterized by using powder X-ray diffraction and scanning electron microscopy.

The morphologies and structures of the products were characterized by field-emission scanning electron microscopy and X-ray diffraction measurements.

The morphologies and the phase structures of the products have been characterized by transmission electron microscopy and X-ray diffraction.

The structures of the products were confirmed by 1H NMR, 13C NMR, 19F NMR, and FT-IR spectroscopy.