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BaCO3 solution (0.1 M) was added to the above well-stirred reaction mixture, and stirring was continued for 12 h.
The solution was stirred for 1 h at room temperature, then H2O was added and stirring was continued for 0.5 h.
Stirring was continued for 12 h.
Stirring was continued for 1 h at 0 °C.
Stirring was continued until the solution transformed to a gel.
Stirring was continued for 12 h at room temperature.
Further stirring was continued for 4 h to make sure the reaction was completed.
Stirring was continued for 3 4 h to allow complete evaporation of organic solvent.
Stirring was continued at the same temperature for the total time shown in the Tables below.
After that, 5 ml acetyl acetone was added and stirring was continued for 15 min.
Stirring was continued at room temperature for 30 min, then phenylisothiocyanate (1.35 g, 1.2 mL, 10 mmol) was added dropwise to this mixture and stirring was continued for another 1 h.
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