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Effect of electrolyte concentration on the stern layer thickness at a charged interface.
This was true for all models considered with or without Stern layer.
The transient double layer dynamics was simulated for low and large electrolyte concentrations using the classical Poisson Nernst Planck (PNP) model with or without a Stern layer, and a modified PNP model with a Stern layer, respectively.
Moreover, the Stern layer needs to be accounted for in order to match predicted specific area capacitance with experimental data.
We show good model-to-equilibrium data fits with reasonable values for fitting parameters such as the Stern layer capacitance, micropore volume, and attraction energy.
We also show the implications of Stern layer conductivity and magnetohydrodynamic influence on system irreversibility through entropy generation analysis due to fluid friction and heat transfer.
The transient double layer dynamics was simulated using the modified Poisson Nernst Planck (MPNP) model with a Stern layer and accounting for the presence of the electrode.
Finally, our original paper, for the first time, solved a modified Poisson Nernst Planck model with a Stern layer for simulating EIS.
This electrokinetic behavior indicates that ethylene glycol molecules adsorb in the Stern layer and affect the electric characteristics of the interface.
Then, the cationic collector DTAC forms an electroneutral complex with the anionic collector NaOL and co-adsorbs on the Stern layer because of the chemisorption of NaOL.
Going beyond the celebrated Debye Hückel linearization, we obtain a closed form analytical expression for velocity and induced streaming potential through the consistent description of finite conductance of the immobilized Stern layer.
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