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The same conclusions can be formed regarding the second step decomposition of MgH2 at 257.86 °C accompanied by the formation of γ.
Apparently, the reduction of oxygen (to hydrogen peroxide) is initiated at cobalt porphyrin centers, and the second step (decomposition of hydrogen peroxide intermediate to water) is pursued at reactive sites (perhaps c-cytochrome) existing within biofilm matrix.
This step decomposition of organic molecules was confirmed by the increasing peaks for water (m/z 18) and carbon dioxide (m/z 44) in the mass spectra (Fig. 8) of analyzed samples.
On the other hand, the activation parameters for the first step decomposition of the BCHMX-TMTA (2.355 J g−1) and CL-20-TMTA mixtures were found to be very close to that of TMTA (1.320 J g−1), strongly indicating that most probably TMTA undergoes decomposes during the first decomposition steps of these mixtures.
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The first-step decomposition of NC-III appeared at 152 °C leaving 98.2%% residue.
In the first-step decomposition of GO appeared at 170 °C leaving wt.
We found that almost the same sharp decline in weight loss was consistent in the range of 500°C to 600°C (single-step decomposition of carbon black powder); this can be attributed to the oxidation behavior of carbonaceous material, including GS, SWCNT, and multi-walled CNT (MWCNT).
The latter can be further decomposed into the effects of cohort turnover (( mathrm{c}mathrm{t} )), migration at working ages (( mathrm{mg} )), and mortality at working ages (( mathrm{m}mathrm{t} )). Figure 3 presents the two-step decomposition of change in the TSR during the whole study period (similar sets of maps for each of the decades can be found in the Appendix, Figures 6, 7, 8, and 9).
The first step decomposition temperature of MgH2 in the mixture at 1 bar is 234 °C; i.e., 50.73 °C lower than the decomposition temperature of MgH2 alone and is due to the formation of the β phase.
Thermal analysis curves revealed decomposition profile of pure CA occurred at 217°C (99.2%) in one step while decomposition of ZCA intercalation compound occurred in two steps, the first one is at around 137°C (weight loss of 13.2%) and the second step is at around 358°C (weight loss of 38.8%).
Moreover, only one complex step for decomposition of TMTA and RDX-TMTA was observed, while at least two steps were found for BCHMX-TMTA and CL-20-TMTA mixtures.
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