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The objective of the present work is to study the influence of the starting composition on the mechanical and fracture properties of zircon mullite composites obtained by direct sintering of consolidated samples by slip cast of concentrated aqueous suspensions in plaster molds.
The internal porosity presented little change as a function of starting composition in the tested intervals.
A range of different fired porcelain tile microstructures was obtained by varying the quartz particle size and content in the starting composition, and the peak firing temperature.
The influence of the starting composition on the mechanical properties of sintered porcelain tile was evaluated based on the linear elastic fracture mechanics.
In Part II the influence of the starting composition on the mechanical properties of sintered porcelain tile was evaluated on the basis of the linear elastic fracture mechanics.
Thermodynamic studies by means of ThermoCalc® software were performed to predict phases stable with the starting composition and also the influence of Fe and C additions.
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For certain starting compositions the measured distillation composition trajectory clearly demonstrate that crossing the distillation boundary is possible.
For certain starting compositions the measured distillation composition trajectories clearly demonstrate that crossing of the distillation boundary is possible.
It was found that the microstructure of these materials could be controlled by the starting compositions and the processing conditions.
The results demonstrated that acid concentration in starting compositions has a great effect on morphologies of the final samples.
Variation of stoichiometry has been studied using powders synthesized by solid state reaction and measuring the Curie temperatures of samples synthesized from batches with different starting compositions.
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