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b A free standing membrane is fully attached to a circular hole with diameter of 2 μm.
Immersion of the film in diluted hydrofluoric acid (2% (v/v)) allowed then the formation of a free standing membrane.
It was found that these membranes tended to detach from the edges of larger microholes, but not smaller ones (Fig. 1). Figure 1 a A free standing membrane is partially detached from a 7.5 μm × 6.5 μm rectangular hole.
Mitochondria have one of the largest standing membrane potentials in the body and their energetic functions are entirely dependent on the regulated movement of electrons and protons within the inner mitochondrion membrane.
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This size dependence is also observed by Cheng et al. [11] who fabricated free standing membranes composed of highly ordered arrays of gold nanoparticles linked by single strand DNA molecules.
Experiments have demonstrated that smaller free standing membranes are structurally and thermally more stable than larger ones [9, 10].
The free standing membranes or self patterned composite films obtained in this investigation may present interesting bio-applications.
Moreover, this work shows that these composite thin films, a few μm thick, can be easily detached as free standing membranes containing photoactive TiO2.
Composite free standing membranes made by solvent casting of polyaniline (PANI) synthesized in the presence of water-soluble polyvinyl alcohol (PVA) as a steric stabilizer, were deposited on solid substrates to yield homogeneous and porous membranes.
In this work, an impedance study was carried out using the 4-electrodes cell arrangement with corrosion products picked up on steel sheet piling immersed for 25 years and analyzed as free standing membranes.
We therefore think that the general conclusions of our work are valid also for free standing membranes.
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