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This work concerns the first stage of combustion in a small, air-staged, wood-chip boiler because comprehensive experimental data on the release of wood-volatiles during thermal conversion of solid biomass on grates are necessary to provide reliable data for the validation and optimization of fuel bed models and gas phase combustion models.
The bipropellant flame was found to exhibit an oscillatory behavior in the second stage of combustion.
Additionally, quenched filament samples collected during the second stage of combustion exhibited large spherical voids.
When advanced stage of combustion is allowed, the deposited films were composed of fine particles with an average diameter between 200 and 400 nm.
Products of the first stage of combustion are nano-grains of NiAl separated by liquid gaps of the Al-Ni melt.
It was shown also that most of the heat released in the second stage of combustion is generated by grain coarsening.
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The latter is particularly important for determining burnout at the final stages of combustion.
Three stages of combustion process are identified as water evaporation, removal and combustion of volatile matters and combustion of char.
Secondly, percolative fragmentation in the late stages of combustion is a rare event under these conditions.
The combined model is tested against reported laminar flow reactor burning profiles of several coal chars at the intermediate stages of combustion and for a single coal char also at the later stages of combustion.
The results are in good agreement with others previously obtained through chemiluminescence imaging for early and intermediate stages of combustion.
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