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The dependence of the apparent diffusion coefficients on the stabilization potential can help understand the dependence of the voltammograms shape on the countercation nature.
The potential at which the electrode was stabilized had a pronounced effect, though causing the activation energy to diminish by increasing the stabilization potential.
It also shows a steady-state passive film thickness, an inverse electrode capacitance and an initial Tafel slope which all increase linearly with the stabilization potential.
Macrocycle 1 displayed a remarkable stabilization potential for c-kit2 whereas 6 was limited in this respect.
The more substituted group adjacent to carbonyl group the better stabilization potential of positive charge it possesses.
Altogether, the FRET melting results demonstrate that we improved on the G-quadruplex stabilization potential of the lead compounds 1 and 3. We also showed the selectivity potential of helical oligoamides with various G-quadruplex targets.
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Apparent diffusion coefficients are evaluated from impedance spectra at different stabilization potentials.
Nyquist diagrams recorded by EIS at the different stabilization potentials show a diffusional tail at low frequencies.
Moreover, an increased chloride concentration causes a flattening in the low frequencies inductive loop in the Nyquist plot recorded at relatively low stabilization potentials.
The temperature dependence of the impedance spectra of Prussian Blue films has been studied at several stabilization potentials between the totally reduced form, Everitt's Salt, and the mixed-valence form, Prussian Blue.
The effect of electrolyte is mostly described as negative factor for nanoparticle's dispersion stabilization: zeta potential and physical stability decrease at increasing the electrolyte concentration.
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